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Moisture Analysis

Applications in which moisture analysis is important include dry air, hydrocarbon processing, pure semiconductor gases, bulk pure gases, dielectric gases such as those in transformers and power plants, and natural gas pipeline transport. Utilizing a variety of techniques, Consolidated Sciences can measure trace moisture in many gases. They include Fourier transform infrared (FTIR) spectroscopy, continuous wave cavity ringdown spectroscopy (CW-CRDS), and quartz crystal microbalance (QCMB) techniques.

The matrix gas, the impurities other than moisture, as well as the amount of sample available will determine the best technique. In particular, natural gas poses a unique situation since it can have very high levels of contaminants as well as corrosives in varying concentrations.

Due to the ubiquitous nature of water vapor and its adsorptive behavior, an accurate determination at single digit ppm (part per million) levels and below generally requires a very large volume of sample as well as a relatively intensive analysis. It is highly recommended that you discuss your specific analysis directly with one of our analysts.

 

List of general moisture analysis capabilities.

Matrix Detection Limit(s)DL(s) (ppm) Technique(s)
Ammonia (NH3) 1–2 ppm 1–2 FTIR
Argon (Ar) 0.01 ppm 0.01 FTIR, CW–CRDS
Arsine (AsH3) 1 – 2 ppm 1 – 2 FTIR
Boron trichloride (BCl3) 1 – 2 ppm 1 – 2 FTIR
Boron trifluoride (BF3) 1 – 2 ppm 1 – 2 FTIR
Carbon dioxide (CO2) 0.05 ppm 0.05 CW–CRDS
Carbon monoxide (CO) 0.05 ppm 0.05 CW–CRDS
Carbon tetrafluoride (CF4) 0.05 ppm 0.05 CW–CRDS
Chlorine (Cl2) 0.05 ppm 0.05 CW–CRDS
Deuterium (D2) < 0.01 ppm < 0.01 FTIR, CW–CRDS, QCMB
Dichlorosilane (SiCl2H2) 1–2 ppm 1–2 FTIR
Difluoroethane (C2H4F2) 1–2 ppm 1–2 QCMB
Difluoromethane (CH2F2) 1–2 ppm 1–2 QCMB
Dimethylamine ((CH3)2NH) 1–2 ppm 1–2 QCMB
Disilane (Si2H6) 1–2 ppm 1–2 FTIR
Ethane (C2H6) 1–2 ppm 1–2 FTIR, QCMB
Ethylene (C2H4) 1–2 ppm 1–2 FTIR, QCMB
Germane (GeH4) 1–2 ppm 1–2 FTIR, QCMB
Germanium tetrafluoride (GeF4) 1–2 ppm 1–2 FTIR
Helium (He) 0.05 ppm 0.05 CW–CRDS
Hexafluoro-1,3-butadiene (C4F6) 0.05 ppm 0.05 CW–CRDS
Hexafluoroethane (C2F6) 0.05 ppm 0.05 CW–CRDS, QCMB
Hydrogen (H2) 0.05 ppm 0.05 CW–CRDS, QCMB
Hydrogen bromide (HBr) 0.05 ppm 0.05 FTIR, CW–CRDS
Hydrogen chloride (HCl) 0.05 ppm 0.05 FTIR, CW–CRDS, QCMB
Hydrogen fluoride (HF) 0.5 – 2.0 ppm 0.5 – 2.0 FTIR
Hydrogen selenide (H2Se) 1–2 ppm 1–2 FTIR
Hydrogen sulfide (H2S) 1–2 ppm 1–2 FTIR
Methane (CH4) 0.05 ppm 0.05 QCMB
Methyl chloride (CH3Cl) 0.05 ppm 0.05 QCMB
Methyl fluoride (CH3F) 0.05 ppm 0.05 QCMB
Neon (Ne) 0.05 ppm 0.05 FTIR, CW–CRDS, QCMB
Nitric Oxide (NO) 1–2 ppm 1–2 FTIR
Nitrogen (N2) 1–2 ppm 1–2 FTIR, CW–CRDS, QCMB
Nitrogen trifluoride (NF3) 0.05 ppm 0.05 FTIR, CW–CRDS, QCMB
Nitrous Oxide (N2O) 0.1 ppm 0.1 CW–CRDS
Octafluorocyclobutane (C4F8) 0.01 ppm 0.01 CW–CRDS
Oxygen (O2) < 0.01 ppm < 0.01 FTIR, CW–CRDS, QCMB
Phosphine (PH3) 0.5 – 2.0 ppm 0.5 – 2.0 FTIR
Propene (C3H6) < 0.05 ppm < 0.05 FTIR, QCMB
Silane (SiH4) 0.5 – 2.0 ppm 0.5 – 2.0 FTIR
Silicon tetrafluoride (SiF4) 0.5 – 2.0 ppm 0.5 – 2.0 FTIR
Sulfur dioxide (SO2) 0.5 – 2.0 ppm 0.5 – 2.0 FTIR
Sulfur hexafluoride (SF6) < 0.01 ppm < 0.01 FTIR, CW–CRDS, QCMB
Trifluoromethane (CHF3) 0.5 – 2.0 ppm 0.5 – 2.0 FTIR, QCMB
Trimethylamine ((CH3)3N) 50 – 100 ppm 50 – 100 FTIR
Trimethylsilane (Si(CH3)3) < 0.05 ppm < 0.05 FTIR, QCMB
 

We recommend discussing your specific analysis directly with one of our analysts. Call us today to discuss your specific needs and visit Getting Started for important information.

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